Product ID:SPRAY PAINTS, 7813 GLOSS WHITE
MSDS Date:06/01/1992
FSC:8010
NIIN:00N062757
MSDS Number: BYGWK

MARTIN-SENOUR CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 16772

MARTIN-SENOUR CO THE DIV SHERWIN-WILLIAMS CO

CHICAGO, IL 60608-5724 US

Cage: 16772

PROPANE

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 15%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

MINERAL SPIRITS; (V M & P NAPHTHA)

CAS: 64475-85-0

RTECS: PY8240000

Fraction By Weight: 5%

OSHA PEL N/K

ACGIH TLV: N/K

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 2%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENE (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 10-15%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL ALCOHOL; (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 1-10%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

ISOBUTYL ALCOHOL; (2-METHYL-1-PROPANOL)

CAS: 78-83-1

RTECS: NP9625000

Fraction By Weight: 2%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL)

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 1-10%

OSHA PEL 50 PPM, S

ACGIH TLV: 25 PPM, S

ACETONE (SARA 313) (CERCLA)

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 48%

OSHA PEL 1000 PPM

ACGIH TLV: 750PPM/1000STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 2%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM/300STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPIONIC ACID, 3-ETHOXY-, ETHYL ESTER;

CAS: 763-69-9

RTECS: UF3325000

Fraction By Weight: 7%

OSHA PEL N/K

ACGIH TLV: N/K

ACETIC ACID, ISOBUTYL ACETATE; (ISOBUTYL ACETATE) (CERCLA)

CAS: 110-19-0

RTECS: AI4025000

Fraction By Weight: 3%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 3-5%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

OCCUP CHEM REPRO HAZ. SEEK CONSULTATION

RTECS: 9999999ZZ

LIST INFO & SAFE HNDLG & EXPOS INFO . ANIMAL

RTECS: 9999999ZZ

EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS &

RTECS: 9999999ZZ

ETHER (EGBE) (EXTRACTED FROM DHHS (NIOSH)

RTECS: 9999999ZZ

INCIN. DEPRESSURIZE CONTR. DISP OF I/A/W

RTECS: 9999999ZZ

GROUNDING PROC. CONTENTS UNDER PRESS. DO NOT

RTECS: 9999999ZZ

SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT

RTECS: 9999999ZZ

INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. USE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT TO EYES, SKIN & RESP SYS.
MAY CAUSE CNS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS
DEATH. HDCH, DIZZ, NAUS, LOSS OF COORD ARE INDICATIONS OF EXCESS
EXPOS TO VAPS/SPRAY MISTS. METHY L ETHYL KETONE MAY INCR CNS EFTS
OF OTHER SOLV. PRLNG OVEREXP TO SOLV MAY CAUSE ADVERSE EFTS TO THE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: LIVER, URINARY, BLOOD FORMING,
CARDIO-VASCULAR & REPRO SYS. RATS EXPOS TO TITANIUM DIOXIDE DUST AT
250MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT
ATTAINABLE IN WORKPLACE. REPORTS HAVE ASSOC RPTD/PRLNG OVEREXP TO
SOLV W/PERM BRAIN & CNS DMG. TOLUENE APPEARS ON THE NAVY LISTING OF
(ING 13)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: REMOVE FROM EXPOS. RESTORE BRTHG. KEEP WARM & QUIET.
SKIN: WASH AFFECTED AREA THORO W/SOAP & WATER. REMOVE CONTAM CLTHG
& LAUNDER BEFORE REUSE. EYES: FLUSH W/LGE AMTS OF WATER FOR AT
LEAST 15 M IN. GET MED ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH
TO AN UNCON PERS. DO NOT INDUCE VOMIT. GIVE SEVERAL GLASSES OF
WATER. SEEK MED ATTN.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.7%
Upper Limits:6.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZ
PREFERABLE. WATER MAY BE USED TO COOL (SUP DAT)
Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT. APPLICATN TO HOT (SUP DAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTENTS EXTREMELY FLAM. KEEP AWAY
FROM HEAT, SPARKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY
IGNITE EXPLO.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA
VENTILATED. DO NOT SMOKE. EXTING ALL FLAMES, PILOT LIGHTS &
HEATERS. TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER
SOURCES OF IGNIT. CONSULT NFPA CODE. USE APPRVD BONDING & (ING 18)

Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED < APPLIC LIM
BY VENT, WEAR NIOSH/MSHA APPRVD PROPERLY FITTED ORG VAP/PARTICULATE
RESP. WHEN SANDING, WIREBRUSHING, ABRADING, BURNING/WELDING DRIED
FILM, WEAR NIOSH/M SHA APPRVD PARTICULATE RESP FOR PROT.
Ventilation:LOC EXHAUST PREFERABLE. GEN EXHAUST ACCEPTABLE IF EXPOS IS
MAINTAINED BELOW APPLIC EXPOS LIM. REFER TO OSHA (SUP DAT)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:AVOID BRTHG VAPS & SPRAY MIST. AVOID CONT
W/SKIN & EYES. WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC: CLSD CONTRS TO PREVENT PRESS BUILD-UP & POSS
AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. EXPLO HAZ: SURF
REQUIRES SPEC PREC. DURING EMER CNDTNS OVEREXP TO DECOMP PROD MAY
CAUSE HLTH H AZ. SYMP MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN.
VENT: STDS 1910.94, 1910.107, 1910.108.

Boiling Pt:B.P. Text:<360F,<182C
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>75

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGREDIENTS SECTION.

Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLIC EPA HAZ WASTE #. WASTE FROM PRODS CONTAINING METHYL ETHYL
KETONE MAY ALSO RE QUIRE TESTING FOR EXTRACTABILITY. DO NOT (ING
17)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.